Blue, green and red LEDs.An ultraviolet GaN LED.Spectrum of a "white" LED clearly showing blue light which is directly emitted by the GaN-based LED (peak at about 465 nanometers) and the more broadband stokes shifted light emitted by the Ce3+:YAG phosphor which extends from around 500 to 700 nanometers.
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LED

A light-emitting diode (LED) is a semiconductor device that emits incoherent narrow-spectrum light when electrically biased in the forward direction. This effect is a form of electroluminescence. more...

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The color of the emitted light depends on the composition and condition of the semiconducting material used, and can be infrared, visible or near-ultraviolet. Rubin Braunstein of the Radio Corporation of America first reported on infrared emission from gallium arsenide (GaAs) and other semiconductor alloys in 1955. Experimenters at Texas Instruments, Bob Biard and Gary Pittman, found in 1961 that gallium arsenide gave off infrared (invisible) light when electric current was applied. Biard and Pittman were able to establish the priority of their work and received the patent for the infrared light-emitting diode. Nick Holonyak Jr. of the General Electric Company developed the first practical visible-spectrum LED in 1962.

LED technology

Physical function

An LED is a unique type of semiconductor diode. Like a normal diode, it consists of a chip of semiconducting material impregnated, or doped, with impurities to create a p-n junction. As in other diodes, current flows easily from the p-side, or anode, to the n-side, or cathode, but not in the reverse direction. Charge-carriers — electrons and electron holes — flow into the junction from electrodes with different voltages. When an electron meets a hole, it falls into a lower energy level, and releases energy in the form of a photon.

The wavelength of the light emitted, and therefore its color, depends on the band gap energy of the materials forming the p-n junction. In silicon or germanium diodes, the electrons and holes recombine by a non-radiative transition which produces no optical emission, because these are indirect bandgap materials. The materials used for an LED have a direct band gap with energies corresponding to near-infrared, visible or near-ultraviolet light.

LEDs are usually constantly illuminated when a current passes through them, but flashing LEDs are also available. Flashing LEDs resemble standard LEDs but they contain a small chip inside which causes the LED to flash with a typical period of one second. This type of LED comes most commonly as red, yellow, or green. Most flashing LEDs emit light of a single wavelength, but multicolored flashing LEDs are available too.

LED development began with infrared and red devices made with gallium arsenide. Advances in materials science have made possible the production of devices with ever-shorter wavelengths, producing light in a variety of colors.

LEDs are usually built on an n-type substrate, with electrode attached to the p-type layer deposited on its surface. P-type substrates, while less common, occur as well. Many commercial LEDs, especially GaN/InGaN, also use sapphire substrate. Substrates that are transparent to the emitted wavelength, and backed by a reflective layer, increase the LED efficiency. The refractive index of the package material should match the index of the semiconductor, otherwise the produced light gets partially reflected back into the semiconductor, where it gets absorbed and turns into additional heat.

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